pH + pOH = 14 (For water at 25°C)
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pH and pOH are measures of the acidity and basicity of a solution. pH is the negative logarithm of the hydrogen ion concentration, while pOH is the negative logarithm of the hydroxide ion concentration. In water at 25°C, they always add up to 14.
The calculator uses the fundamental relationship:
Where:
Explanation: This relationship comes from the ion product of water (Kw = [H+][OH-] = 1×10⁻¹⁴ at 25°C).
Details: pH is critical in many chemical and biological processes. It affects enzyme activity, chemical solubility, and biological functions. pOH is useful when working with basic solutions.
Tips: Enter either pH or pOH value (between 0-14), and the calculator will compute the other value. Both fields can't be filled simultaneously.
Q1: Why does pH + pOH equal 14?
A: This comes from the ion product of water (Kw = [H+][OH-] = 1×10⁻¹⁴ at 25°C). Taking negative logs gives pH + pOH = pKw = 14.
Q2: Does this relationship hold at all temperatures?
A: No, the constant changes with temperature. At 37°C (body temperature), pH + pOH ≈ 13.6.
Q3: What is a neutral pH?
A: At 25°C, neutral pH is 7 (equal concentrations of H+ and OH-). The neutral point changes with temperature.
Q4: How precise are pH measurements?
A: pH meters typically have ±0.01 precision. For most applications, 2 decimal places are sufficient.
Q5: Can I use this for non-aqueous solutions?
A: No, this relationship is specific for aqueous solutions. Other solvents have different ion products.